Although Chris Pine is primarily an actor, he did play a musician in the movie Small Town Saturday Night. He performed a song entitled Someday Came Today.
Also he some singing in the movie Into the Woods, where he played Prince Charming. He did impressive job performing.
In 2016, Chris Pine was invited by Barbara Streisand to perform I’ll Be Seeing You / I’ve Grown Accustomed to Her Face.
Here are two songs below of him showing some incredible vocals!